2-Phenyl-3-(trimethylsilyl)propan-1-aminium chloride
نویسندگان
چکیده
The title compound, C(12)H(22)NSi(+)·Cl(-), contains two formula units in the asymmetric unit and is a hydro-chloride salt in which the amine N atom is protonated and the NH(3) (+) group forms hydrogen bonds with the Cl(-) anion, forming a ribbon in the c-axis direction.
منابع مشابه
N-(2-Benzoylethyl)propan-2-aminium chloride
In the title salt, C(12)H(18)NO(+)·Cl(-), N-H⋯Cl inter-actions between the free chloride anions and the organic cations connect the mol-ecules into hydrogen-bond dimers, forming a R(2) (2)(8) motif. The dimers are linked by C-H⋯O hydrogen bonds into chains extending along [301]. The carbonyl group is co-planar with the phenyl ring [C-C-C=O torsion angle = -3.3 (7)°]. The side chain has an E con...
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THE TITLE CRYSTAL STRUCTURE (SYSTEMATIC NAME: N-methyl-1-phenyl-propan-2-aminium chloride), C(10)H(16)N(+)·Cl(-), was orginally determined by Simon, Bocskei & Torok [Acta Pharm. Hung. (1992). 62, 225-230] and Yao, Kan & Wang [Huaxue Shijie (1999). 40, 568-570] at room temperature but no atomic coordinates are available for these determinations. The mol-ecule has inter-est with respect to biolog...
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THE TITLE COMPOUND [SYSTEMATIC NAME: N-methyl-3-(1-naphth-yloxy)-3-(2-thien-yl)propan-1-aminium chloride], C(18)H(20)NOS(+)·Cl(-), was crystallized from 1,4-dioxane. Twofold rotational disorder exhibited by the thio-phene ring in a 0.580 (5):0.420 (5) ratio represents two different conformations of the mol-ecule that exist in the same crystal form. The crystal structure contains strong N-H⋯Cl h...
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In the title compound, C(13)H(20)NO(+)·Cl(-), the protonated amino N atom is hydrogen bonded to the chloride anion. N-H⋯Cl hydrogen bonds link the anions and cations into dimers, which are connected by C-H⋯O hydrogen bonds, forming supra-molecular chains extending along [100].
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In the title compound, C(11)H(14)N(3)O(+)·Cl(-)·CH(4)N(2)S, the components are connected into a two-dimensional polymeric structure parallel to (001) via N-H⋯Cl, N-H⋯O, N-H⋯S and C-H⋯S hydrogen bonds. The dihedral angle between the phenyl and 2,3-dihydro-1H-pyrazole rings is 44.96 (7)°.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011